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Bomb Calorimeter

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Submitted By dha102
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Bomb Calorimeter
(The Resonance Energy of an Arene Hydrocarbon)
David Ha dha@xula.edu Partner: Melissia Porter and Chris Dunlock
Experiment Date:
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Abstract: In this experiment a bomb calorimeter was used to measure the heat evolved during the combustion of the samples at constant volumes. Before the process was done the bomb calorimeter was calibrated with a benzoic acid tablet. The reason benzoic acid was used is because the other samples are aromatic structures just like it. The calculated value for heat capacity is 10.24kJK while the value of energy of combustion of CDDT and TBDMB is -7225.71kJmol, and -7010.37kJmol respectively. Using the energy of combustion of the samples the values of molar enthalpy is calculated to be -7223.2kJmol and -7007.9kJmol of CDDT and TBDMB accordingly.

Introduction: The purpose of the experiment is to determine the resonance energy of the aromatic hydrocarbon using the bomb calorimeter process. In this process the molar enthalpy of combustion was calculated using the data that was collected. Prior to the calculations a calibration is needed so that the heat capacity of the calorimeter can be calculated, which will be used to calculate the energy of combustion of the two samples. With the combustion reaction that is happening with in the bomb, the data collected can be used to determine the potential maximum heat released by a fuel. A test sample of a known mass is combusted under standard conditions while the volume remains constant within pure oxygen atmosphere.

Experimental: In this experiment each sample was weighed with the analytical scale, which was no more than 1.000g because the more sample used then the risk of the bomb being actually a “bomb”. Once that is weighed out, it was placed in the fuel capsule where the nichrome wire was then placed carefully where it was touching the

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