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Energy and Mass Balance

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HYSYS Assignment 1
Exercise 1

From the article Process Selection and Optimisation Studies – North Rankin ‘A’ by K.R. Gammie, we are told that the operating temperature for a 1 year flowing condition, the temperature is 76°C and has a pressure of 24.2 MPa. At this flowing condition, we can see that we have a point far above the saturation dome; therefore the fluid is single phase.
For a 10 year flowing condition, the temperature is given as 96°C and has a pressure of 13.2 MPa. At this flowing condition, we have a point that is just inside the saturation dome which means that the fluid is in 2 phases.

Importance of the overlap.
We can see from the above graph that the vapour stream is significantly flatter than the feed and vapour streams. This is because the vapour and feed stream have similar component compositions. There is quite a large overlap of the liquid and vapour streams between -150°C and 50°C which indicates that there is a large proportion of gas in both these streams. All three of the phase envelopes overlap at some point because they all consist of the same components.
The flatness of the liquid stream can be attributed to the fact that the liquid has a lower vapour pressure at any given temperature, than the vapour and feed streams. The liquid stream also contains heavier hydrocarbons which exhibit a lower pressure than the vapour and gas streams which consist of lighter hydrocarbons.
The bubble point curve of the liquid stream intersects with the dew point of the vapour stream curve at 55°C and 11 MPa, which are the NRA process conditions. At this point, the fluid is separated into 2 phases which is consistent with our separator conditions.

| Mole Compositions | Component | Gas | Liquid | Nitrogen | 3.15e-3 | 7.26e-4 | Carbon Dioxide | 1.77e-2 | 1.28e-2 | Methane | 0.838 | 0.380 | Ethane | 7.41e-2 | 8.13e-2 | Propane |

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