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Plastic Packaging Resin Identification Codes

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Submitted By jennice
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UNIVERSITI TUNKU ABDUL RAHMAN
UDEC3304
Polymer Chemistry

ASSIGNMENT

Title | Plastic Packaging Resin Identification Codes | Name | CHONG LING MIN | Student ID | 1103206 | Lecturer’s name | Dr. Chee Swee Yong | Date | 28th June 2013 |

Table contents 1. Background…………………………………………….pg.1 2. Resin identification coding system…………………….pg.2 3. Symbols and polymer names…………………………..pg.2 4. Classification of polymer type…………………………pg.2 5. Applications before and after recycling……………..pg.3-5 6. Molecular formula and hazards……………………...pg.3-5 7. Conclusion……………………………………………pg.5 8. References……………………………………………pg.6

Background
In modern science and technology, most of the plastic packaging is made with different codes of resin. The Resin Identification Codes assigns these resins with a number from 1 to 6, which are polyethylene terephthalate (PETE); high density polyethylene (HDPE); polyvinyl chloride (PVC or vinyl); low density polyethylene (LDPE); polypropylene (PP); or polystyrene (PS). The coding system also includes a seventh code which is labeled as "other."
The principal roles of coding system for these resins are to provide a consistent national system to help consumers and manufacturers efficiently identify and sort plastics for recycling. The coding system is also enable individuals to maintain and perform quality control before recycling, which help to make sure the recycled plastic is as homogenous as possible. Hence, all these seven codes indicate the product possesses various properties, while for the seventh code was developed to address legislative demands in some states for fulfilling certain size and functional parameters resins. The purpose of having these polymer plastics is to protect food products from outside influences and damage. Traceability, convenience, and tamper indication are secondary important functions. The goal of food packaging is to contain food in a cost-effective way that satisfies industry requirements and consumer desires, maintains food safety, and minimizes environmental impact.

Table of Resin Identification Codes: Recycling Number | Symbol | Polymer Name | Type of Polymerization | Structure | Molecular formula | 1 |
(PET) | Polyethylene Terephthalate | Condensation | (-CO-C6H4-CO-O-CH2-CH2-O-)n | (C10H8O4)n | 2 |
(HDPE) | High Density Polyethylene | Addition | –(CH2-CH2)n– | (C2H4)n | 3 |
(PVC) | Polyvinyl Chloride | Addition | –(CH2-CHCl)n– | (C2H3Cl)n | 4 |
(LDPE) | Low Density Polyethylene | Addition | –(CH2-CH2)n– | (C2H4)n | 5 |
(PP) | Polypropylene | Addition | –[CH2-CH(CH3)]n– | (C3H6)n | 6 |
(PS) | Polystyrene | Addition | –[CH2-CH(C6H5)]n– | (C8H8)n | 7 |
(OTHER) | Other plastics, including acrylic, acrylonitrile butadiene styrene, fiberglass, nylon, polycarbonate, and polylactic acid | Condensation | - | - |

Table 2: Symbol of resins with their application before and after recycling, hazards as well. Symbol | Packaging application | Recycled product | Hazard | (PET) | -Plastic soft drink, water, sports drink, beer, mouthwash, catsup and salad dressing bottles. -Peanut butter, pickle, jelly and jam jars.-Ovenable film and ovenable prepared food trays. | -Fiber, tote bags, clothing, film and sheet-food and beverage containers-carpet, strapping, fleece wear, luggage and bottles. | -no known hazards-dry resins are nuisance dust hazards-heating resin above 1950C may cause gas and vapor that are potent irritants-it may cause irritation to the upper respiratory tract, coughing, and congestion.-molten resin will cause thermal burns.-it may cause temporary itching and eyes redness.-chronic toxicity | (HDLP) | -Milk, water, juice, cosmetic, shampoo, dish and laundry detergent bottles- yogurt and margarine tubs-cereal box liners-grocery, trash and retail bags. | -Liquid laundry detergent, shampoo, conditioner and motor oil bottles-pipe, buckets, crates, flower pots, garden edging, film and sheet, recycling bins, benches, dog houses, plastic lumber, floor tiles, picnic tables, fencing. | -no known hazards-non-biodegradable-low toxicity-dust may have irritant effect on eyes.-chronic effect when long term exposure-it can melt and burn in fire. | (PVC) | -Clear food and non-food packaging-medical tubing- wire and cable insulation-film and sheet, construction products such as pipes, fittings, siding, floor tiles, carpet backing and window frames. | -Packaging, loose-leaf binders, decking, paneling, gutters, mud flaps, film and sheet-floor tiles and mats, resilient flooring, cassette trays, electrical boxes, cables, traffic cones, garden hose, mobile home skirting. | -no known hazards-ingestion of large amount may cause nausea and vomiting.-it may have an irritant effect on abraded skin. | (LDPE) | -Dry cleaning, bread and frozen food bags -squeezable bottles, e.g. honey, mustard | -Shipping envelopes, garbage can liners, floor tile, furniture, film and sheet, -compost bins, paneling, trash cans, landscape timber, lumber | -no known hazards-resins or dust may cause irritation or corneal injury.-vapor from heating resin may cause mild discomfort and redness of the eyes.-it has very low toxicity. -non-biodegradable-it may represent a choking hazard if ingested by waterfowl or aquatic life-it creates an industrial slipping hazard | (PP) | -Catsup bottles- yogurt containers -margarine tubs-medicine bottles | -Automobile battery cases, signal lights, battery cables, brooms, brushes, ice scrapers, oil funnels, bicycle racks, rakes, bins, pallets, sheeting, trays. | -no known hazards-molten material will cause thermal burns.-it will have mechanical irritation only.-stock shapes are not respirable, avoid breathing dust.-thermal decomposition will be irritating to the mucus membrane and respiratory tract. | (PS) | -Compact disc jackets, -food service applications-grocery store meat trays-egg cartons, aspirin bottles, cups, plates, cutlery. | -Thermometers, light switch plates, thermal insulation, egg cartons, vents, desk trays, rulers, license plate frames, foam packing, foam plates, cups, utensils | -Dust may cause mechanical irritation. -fire / explosion hazards -flammability under right conditions. | (OTHER) | -Three and five gallon reusable water bottles-some citrus juice and catsup bottles. | -Bottles, plastic lumber applications. | -it depends on resins or combination of resin.- resins rarely induce skin allergies or irritation.-hazardous decomposition products may include oxides of carbon and various hydrocarbon fragments.-hazardous polymerization may occur. |

Conclusion:
The Resin Identification Codes assigns these resins are very useful for providing consumers and manufacturers efficiently identify and sort plastics for recycling. The different codes of resins have different properties as well as characteristics of making as application before and after recycling. So far, there has no known of serious hazards for packaging resins.

References:

1. Av.com. 2004. Guide to the Safe Handling of PVC Resin Supplied by Australian Vinyls. [online] Available at: http://www.av.com.au/Assets/16/1/GuidetotheSafeHandlingOfCorvicPVCResin.pdf [Accessed: 10th Jun 2013].

2. Cityplastics,com. 2009. MATERIAL SAFETY DATA SHEET, POLYPROPYLENE. [online] Available at: http://www.cityplastics.com.au/pdf/polypropylene%20msds.pdf [Accessed: 19 Jun 2013].

3. Interplas.com. 1988. Resin Identification Codes - Plastic Recycling Codes. [online] Available at: http://www.interplas.com/help/glossary-resin-identifiacation [Accessed: 8th Jun 2013].

4. Minigrip.com. 1988. SPI Resin Identification Codes: Reclosable Polyethylene Packaging & Zipper Bags: Minigrip. [online] Available at: http://www.minigrip.com/resin-identification-codes.html [Accessed: 19 Jun 2013].

5. Msdssearch.dow.com. 2009. DOW™ Low Density Polyethylene (LDPE) Resins. [online] Available at: http://msdssearch.dow.com/PublishedLiteratureDOWCOM/dh_02b8/0901b803802b851f.pdf?filepath=productsafety/pdfs/noreg/233-00587.pdf&fromPage=GetDoc [Accessed: 10th Jun 2013].

6. Nationalpipe.com. 2011. MATERIAL SAFETY DATA SHEET - HDPE. [online] Available at: http://www.nationalpipe.com/HDPE%20MSDS.pdf [Accessed: 10th Jun 2013].

7. Setonresourcecenter.com. 2000. MSDS - 2202. [online] Available at: http://www.setonresourcecenter.com/msdshazcom/htdocs/MSDS/A/ARCHIVE/wcd0000a/wcd00af4.htm [Accessed: 8th Jun 2013].

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