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Crystal Chemical Relationship

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This written paper will discuss a total of three points. Namely the crystal chemical relationship between quartz (SiO2) and FePO4, the symmetry relationship between FePO4 polymorph, its dependence on temperature and also the mechanism of the symmetry change for the FePO4 polymorphs. Respective paragraphs of this paper will touch on each point listed above. Firstly, the crystal chemical relationshop between quartz (SiO2) and FePO4 will be discussed. The cell parameters of the α-phase FePO4 has a non linear relationshop with the temperature, the cell parameters and atomic coordinates also tend to become similar to the value shown in the β-phase, when temperatures are high. There are two factors that affects the thermal expansion. They are tilt …show more content…
This increase is however non-linear. The rise in temperature will also cause an increase in volume of FEPO4. The c/a ratio, on the other hand, has an inverse relationship with temperature. As stated above, there will be an increase in Fe-O-P bond angle. When the temperature reaches nearly 980K, the structural parameters will be closer towards the higher α-phase. A change occurs from α to β phase. The changes in the β phase would however not be significant. However, in the β phase, there is a higher degree of disorder which is correlated to the intertetrahedral tilt angle. This intertetrahedral tilt angle is the average of the individual angles in the molecule. As the temperature gradually hits 980K, the intertetrahedral tilt angle will drop. This can be seen in the first order transition where discontinues can be seen. The α-phase has greater variations in the vibrations observed. The β phase is different and has no thermal expansion due to the lack of vibrations. The stability of the bridging angles and tilt angles are much lesser than that of the thermal instability stated above. Tetrahdral distortion is thus influenced by the temperature. With rising temperature, the distortion level increases as well. The tetrehedral distortion affecrts the bond length and bond angle in FEPO4 and PO4. The structure of tetrahedrons are rigid and it is there crucial in identifying the distortion level of tetrahedrals. As such, the tetrahedral tilt has an effect on the distortion. In other words, it is the result of the tetrahdral tilt. The most important factor that affects thermal expansion is the changes in the Fe-O-P angles which leads to angular variations. The temperature level is thus dependent on the amount of angular variations of angles. In conclusion, the thermal stability of the crystal structure can be caused by many different

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