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Typical Products and Uses of Titanium

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Typical Products and Uses of Titanium Due to Titanium’s amazing properties such as corrosion resistance, high strength-to-weight ratio, low density, high heat resistance, high fatigue resistance, high crack resistance and biocompatibility; it is widely used in various industries (Moiseyev, 2006). Titanium is often combined with other metals such as aluminum, vanadium, copper, iron, manganese and molybdenum to create alloys of improved grain size and hardness (Clifford, 1968). Titanium mill products: titanium foil, sheet, wire, and rod are useful in the aerospace, marine, military and other industries. Titanium powder is also used in pyrotechnics to produce silver sparks (Helmenstine, n.d.). Titanium is commonly consumed, meaning, about 95% of titanium ore extracted from the Earth is being refined into the form of titanium dioxide (TiO2), a white permanent pigment used in paints, paper, toothpaste, and plastics (Smook 2002). As titanium oxide, it is used as air purifiers (as a filter coating) to coat windows on buildings so that when titanium oxide becomes exposed to UV light (either solar or artificial) and moisture in the air, reactive redox species like hydroxyl radicals are produced so that they can purify the air or keep window surfaces clean (Stevens et. al., 1998). Also, just recently, 18-year-old Eesha Khare, a senior at Lynbrook High School, designed, synthesized and characterized a core-shell nanorod electrode capacitor (with a hydrogenated titanium dioxide core and polyaniline shell) that retained a supercapacitor's energy density and long life (Adhikari, 2013). The proponents, however, limit the scope of their research into titanium alloy mill products used in the aerocraft industry since two thirds of all titanium metal produced is used in aircraft engines and frames (Emsley ,2001). In this specific industry, titanium alloys are used in making aircrafts, armor plating, spacecraft, and missiles (Krebs, 2006). In particular, titanium alloys are used to produce aerospace components like critical structural parts, fire walls, landing gear, exhaust ducts (helicopters), and hydraulic systems. The SR-71 "Blackbird" was one of the first aircrafts to make extensive use of titanium within its structure. An estimated 59 metric tons (130,000 pounds) are used in the Boeing 777, 45 in the Boeing 747, 18 in the Boeing 737, 32 in the Airbus A340, 18 in the Airbus A330, and 12 in the Airbus A320. The Airbus A380 may use 77 metric tons, including about 11 tons in the engines (Sevan, 2006). In engine applications, titanium is used for rotors, compressor blades, hydraulic system components, and nacelles. The titanium 6AL-4V alloy accounts for almost 50% of all alloys used in aircraft applications (Donachie, 1988), so the research focuses on this specific alloy. Titanium Ti–6Al–4V alloy is the most important and widely used titanium alloy because of their high strength to weight ratio, good corrosion resistance, excellent fracture toughness and attractive mechanical properties which make it an ideal choice for many aerospace applications. (Venkateswarlu, et. al.,2013)

Processes appropriate for the material
Unlike other compounds, pure titanium cannot be extracted by simply reducing its dioxide since it reacts with oxygen at high temperatures (Stwertka, 1988). The extraction and processing of titanium metal occurs in 4 major steps: reduction of titanium ore into sponge; melting of sponge, or sponge plus a master alloy to form an ingot; primary fabrication, where an ingot is converted into general mill products such as billet, bar, plate, sheet, strip, and tube; and secondary fabrication of finished shapes from mill products (Donachie, 1988).
Titanium may be extracted and processed through different processes, but the two most widely used are the Kroll Process and FFC Cambridge process.
Kroll Process is a complex and expensive batch process developed in 1946 by William Justin Kroll. The expensiveness of titanium is mainly due to its processing (if Kroll process was used), which makes use of the expensive magnesium metal. In the Kroll process, the oxide is first converted to chloride through carbochlorination, whereby chlorine gas is passed over red-hot rutile or ilmenite in the presence of carbon to make titanium chloride TiCl4. This is condensed and purified by fractional distillation and then reduced with 800 °C molten magnesium in an argon atmosphere (Columbia Encyclopedia, 2000-2006). It may be summarized in the following equation: 2Mg(l) + TiCl4(g) → 2MgCl2(l) + Ti(s) [T = 800-850 °C]. The resulting porous metallic titanium sponge is purified by leaching or heated vacuum distillation. The sponge is jackhammered out, crushed, and pressed before it is melted in a consumable electrode vacuum arc furnace. The melted ingot is allowed to solidify under vacuum. It is often remelted to remove inclusions and ensure uniformity. These melting steps add to the cost of the product. Titanium is about six times as expensive as stainless steel. (Kroll, 1940)
Meanwhile, the FFC Cambridge process, a recently developed method, may eventually replace the Kroll process. The FFC Cambridge process was developed by George Z. Chen, Derek J. Fray and Tom W. Farthing between 1996 and 1997 in the University of Cambridge. According to Chen, et. al, tThe FFC Cambridge process usually takes place between 900–1100 °C, with an anode (usually carbon) and a cathode (oxide being reduced) in a bath of molten Calcium Chloride CaCl2. Depending . The cathode is then polarized to a more negative voltages versus the anode used through running a voltage between the anode and cathode. When polarized, the oxide releases oxygen ions into the CaCl2 salt, which exists as CaO. When negative voltages are reached, it is possible that the cathode would begin to produce Calcium (which is soluble in CaCl2). Calcium is highly reductive and would further strip oxygen from the cathode, resulting in calciothermic reduction (Chen, et. al., 2000). Thus, the calciothermic reduction would appear as: TiO2 + 2Ca → Ti + 2CaO.
After extraction, the titanium would be alloyed depending on the preferred alloy production. In the case of the alloy Ti 6Al-4V, Titanium had to be alloyed with Aluminum, Vanadium, Carbon, Nitrogen, Oxygen, Hydrogen, Iron and Yttrium in certain amounts. (Retrieved from: http://www.rolledalloys.com/alloys/titanium-alloys/6al-4v/en/)
References:
Adhikari, Richard. 2013. “Teenager's Power Storage Project Lights Up Science World.” TechNewsWorld. Retrieved from: http://www.technewsworld.com/story/78085.html
Chen, George Zheng; Fray, Derek J.; Farthing, Tom W. (2000). "Direct electrochemical reduction of titanium dioxide to titanium in molten calcium chloride". Nature 407 (6802): 361–364. Bibcode:2000Natur.407..361C. doi:10.1038/35030069. PMID 11014188.
Donachie, Matthew Jr. (1988). TITANIUM: A Technical Guide. Metals Park, OH: ASM International. p. 13. ISBN 0-87170-309-2.
Emsley, John (2001). "Titanium". Nature's Building Blocks: An A-Z Guide to the Elements. Oxford, England, UK: Oxford University Press. ISBN 0-19-850340-7. p. 454
Hampel, Clifford A. (1968). The Encyclopedia of the Chemical Elements. Van Nostrand Reinhold. p. 738. ISBN 0-442-15598-0.
Helmenstine, Anne Marie. n.d. “Titanium - Elements in Fireworks Retrieved from http://chemistry.about.com/od/fireworkspyrotechnics/a/titaniumfire.htm
Krebs, Robert E. (2006). The History and Use of Our Earth's Chemical Elements: A Reference Guide (2nd edition). Westport, CT: Greenwood Press. ISBN 0-313-33438-2.
Kroll, W. J., “The Production of Ductile Titanium” Transactions of the Electrochemical Society volume 78 (1940) 35–47.
Moiseyev, Valentin N. (2006). Titanium Alloys: Russian Aircraft and Aerospace Applications. Taylor and Francis, LLC. p. 196. ISBN 978-0-8493-3273-9.
Sevan, Vardan (2006-09-23). "Rosoboronexport controls titanium in Russia". Sevanco Strategic Consulting.
Smook, Gary A. (2002). Handbook for Pulp & Paper Technologists (3rd edition). Angus Wilde Publications. p. 223. ISBN 0-9694628-5-9. Retrieved from http://www.berkeleypoint.com/learning/titanium.html
Stevens, Lisa; Lanning, John A.; Anderson, Larry G.; Jacoby, William A.; Chornet, Nicholas (June 14 – 18, 1998). "Photocatalytic Oxidation of Organic Pollutants Associated with Indoor Air Quality". Air & Waste Management Association 91st Annual Meeting & Exhibition, San Diego.
Stwertka, Albert (1998). "Titanium". Guide to the Elements (Revised ed.). Oxford University Press. pp. 81–82. ISBN 0-19-508083-1.
Venkateswarlu, V.; Tripathy, D.; K. Rajagopal; K. Thomas Tharian; P.V. Venkitakrishnan. 2013. “Failure analysis and optimization of thermo-mechanical process parameters of titanium alloy (Ti–6Al–4V) fasteners for aerospace applications.” Case Studies in Engineering Failure Analysis Volume 1, Issue 2, April 2013, Pages 49–60
"Titanium". Columbia Encyclopedia (6th ed.). New York: Columbia University Press. 2000–2006. ISBN 0-7876-5015-3.
Rolled alloys. Retrieved from: http://www.rolledalloys.com/alloys/titanium-alloys/6al-4v/en/
United States Geological Survey. "USGS Minerals Information: Titanium".

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